相平衡、相图和相变:其热力学基础 (瑞典)希勒特(M. Hillert) 北京大学出版社【.正版】 pdf mobi 下载 kindle 115盘 chm 阿里云 rb

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Preface to second edition page i

Preface to first edition ii

1 Basic concepts of thermodynamics

　1.1 External state variables

　1.2 Internal state variables

　1.3 The first law of thermodynamics

　1.4 Freezing-in conditi***

　1.5 Reversible and irreversible processes

　1.6 Second law of thermodynamics

　1.7 Condition of internal equilibrium

　1.8 Driving force

　1.9 Combined first and second law

　1.10 General conditi*** of equilibrium

　1.11 Characteristic state functi***

　1.12 Entropy

2 Manipulation of thermodynamic quantities

　2.1 Evaluation of one characteristic state function from another

　2.2 Internal variables at equilibrium

　2.3 Equati*** of state

　2.4 Experimental conditi***

　2.5 Notation for partial derivatives

　2.6 Use of various derivatives

　2.7 Comparison between CV and CP

　2.8 Change of independent variables

　2.9 Maxwell relati***

3 Systems with variable compositio

　3.1 Chemical potential

　3.2 Molar and integral quantities

　3.3 More about characteristic state functi***

　3.4 Additivity of extensive quantities. Free energy and exergy

　3.5 Various forms of the combined law

　3.6 Calculation of equilibrium

　3.7 Evaluation of the driving force

　3.8 Driving force for molecular reacti***

　3.9 Evaluation of integrated driving force as function of

　T or P

　3.10 Effective driving force

4 Practical handling of multicomponent systems

　4.1 Partial quantities

　4.2 Relati*** for partial quantities

　4.3 Alternative variables for compositio

　4.4 The lever rule

　4.5 The tie-line rule

　4.6 Different sets of components

　4.7 C***titution and c***tituents

　4.8 Chemical potentials in a phase with sublattices

5 Thermodynamics of processes

　5.1 Thermodynamic treatment of kinetics of

　internal processes

　5.2 Transformation of the set of processes

　5.3 Alternative methods of transformatio

　5.4 Basic thermodynamic c***iderati*** for processes

　5.5 Homogeneous chemical reacti***

　5.6 Transport processes in discontinuous systems

　5.7 Transport processes in continuous systems

　5.8 Substitutional diffusio

　5.9 Onsager’s extremum principle

6 Stability

　6.1 Introductio

　6.2 Some necessary conditi*** of stability

　6.3 Sufficient conditi*** of stability

　*** Summary of stability conditi***

　6.5 Limit of stability

　6.6 Limit of stability against fluctuati*** in compositio

　6.7 Chemical capacitance

　6.8 Limit of stability against fluctuati*** of

　internal variables

　6.9 Le Chatelier’s principle

7 Applicati*** of molar Gibbs energy diagrams

　7.1 Molar Gibbs energy diagrams for binary systems

　7.2 Instability of binary soluti***

　7.3 Illustration of the Gibbs–Duhem relatio

　7.4 Two-phase equilibria in binary systems

　7.5 Allotropic phase boundaries

　7.6 Effect of a pressure difference on a two-phase

　equilibrium

　7.7 Driving force for the formation of a new phase

　7.8 Partitionless transformation under local equilibrium

　7.9 Activation energy for a fluctuatio

　7.10 Ternary systems

　7.11 Solubility product

8 Phase equilibria and potential phase diagrams

　8.1 Gibbs’ phase rule

　8.2 Fundamental property diagram

　8.3 Topology of potential phase diagrams

　8.4 Potential phase diagrams in binary and multinary systems

　8.5 Secti*** of potential phase diagrams

　8.6 Binary systems

　8.7 Ternary systems

　8.8 Direction of phase fields in potential phase diagrams

　8.9 Extremum in temperature and pressure

9 Molar phase diagrams

　9.1 Molar axes

　9.2 Sets of conjugate pairs containing molar variables

　9.3 Phase boundaries

　9.4 Secti*** of molar phase diagrams

　9.5 Schreinemakers’ rule

　9.6 Topology of sectioned molar diagrams

10 Projected and mixed phase diagrams

　10.1 Schreinemakers’ projection of potential phase diagrams

　10.2 The phase field rule and projected diagrams

　10.3 Relation between molar diagrams and Schreinemakers’

　projected diagrams

　10.4 Coincidence of projected surfaces

　10.5 Projection of higher-order invariant equilibria

　10.6 The phase field rule and mixed diagrams

　10.7 Selection of axes in mixed diagrams

　10.8 Konovalov’s rule

　10.9 General rule for singular equilibria

11 Direction of phase boundaries

　11.1 Use of distribution coefficient

　11.2 Calculation of allotropic phase boundaries

　11.3 Variation of a chemical potential in a two-phase field

　11.4 Direction of phase boundaries

　11.5 Congruent melting points

　11.6 Vertical phase boundaries

　11.7 Slope of phase boundaries in isothermal secti***

　11.8 The effect of a pressure difference between two phases

12 Sharp and gradual phase transformati***

　12.1 Experimental conditi***

　12.2 Characterization of phase transformati***

　12.3 Microstructural character

　12.4 Phase transformati*** in alloys

　12.5 Classification of sharp phase transformati***

　12.6 Applicati*** of Schreinemakers’ projectio

　12.7 Scheil’s reaction diagram

　12.8 Gradual phase transformati*** at fixed compositio

　12.9 Phase transformati*** controlled by a chemical potential

13 Transformati*** in closed systems

　13.1 The phase field rule at c***tant compositio

　13.2 Reaction coefficients in sharp transformati***

　for p = c 　

　13.3 Graphical evaluation of reaction coefficients

　13.4 Reaction coefficients in gradual transformati***

　for p = c

　13.5 Driving force for sharp phase transformati***

　13.6 Driving force under c***tant chemical potential

　13.7 Reaction coefficients at c***tant chemical potential

　13.8 Compositional degeneracies for p = c

　13.9 Effect of two compositional degeneracies for p = c .　

14 Partitionless transformati***

　14.1 Deviation from local equilibrium

　14.2 Adiabatic phase transformatio

　14.3 Quasi-adiabatic phase transformatio

　14.4 Partitionless transformati*** in binary system

　14.5 Partial chemical equilibrium

　14.6 Transformati*** in steel under quasi-paraequilibrium

　14.7 Transformati*** in steel under partitioning of alloying elements

15 Limit of stability and critical phenomena

　15.1 Transformati*** and transiti***

　15.2 Order–disorder transiti***

　15.3 Miscibility gaps

　15.4 Spinodal decompositio

　15.5 Tri-critical points

16 Interfaces

　16.1 Surface energy and surface stress

　16.2 Phase equilibrium at curved interfaces

　16.3 Phase equilibrium at fluid/fluid interfaces

　1*** Size stability for spherical inclusi***

　16.5 Nucleatio

　16.6 Phase equilibrium at crystal/fluid interface

　16.7 Equilibrium at curved interfaces with regard to compositio

　16.8 Equilibrium for crystalline inclusi*** with regard to compositio

　16.9 Surface segregatio

　16.10 Coherency within a phase

　16.11 Coherency between two phases

　16.12 Solute drag

17 Kinetics of transport processes

　17.1 Thermal activatio

　17.2 Diffusion coefficients

　17.3 Stationary states for transport processes

　17.4 Local volume change

　17.5 Composition of material crossing an interface

　17.6 Mechanisms of interface migratio

　17.7 Balance of forces and dissipatio

18 Methods of modelling

　18.1 General principles

　18.2 Choice of characteristic state functio

　18.3 Reference states

　18.4 Representation of Gibbs energy of formatio

　18.5 Use of power series in T

　18.6 Representation of pressure dependence

　18.7 Application of physical models

　18.8 Ideal gas

　18.9 Real gases

　18.10 Mixtures of gas species

　18.11 Black-body radiatio

　18.12 Electron gas

19 Modelling of disorder

　19.1 Introductio

　19.2 Thermal vacancies in a crystal

　19.3 Topological disorder

　19.4 Heat capacity due to thermal vibrati***

　19.5 Magnetic contribution to thermodynamic properties

　19.6 A *** physical model for the magnetic contributio

　19.7 Random mixture of atoms

　19.8 Restricted random mixture

　19.9 Crystals with stoichiometric vacancies

　19.10 Interstitial soluti***

20 Mathematical modelling of solution phases

　20.1 Ideal solutio

　20.2 Ming quantities

　20.3 Excess quantities

　20.4 Empirical approach to substitutional soluti***

　20.5 Real soluti***

　20.6 Applicati*** of the Gibbs–Duhem relatio

　20.7 Dilute solution appromati***

　20.8 Predicti*** for soluti*** in higher-order systems

　20.9 Numerical methods of predicti*** for higher-order systems

21 Solution phases with sublattices

　21.1 Sublattice solution phases

　21.2 Interstitial soluti***

　21.3 Reciprocal solution phases

　21.4 Combination of interstitial and substitutional solutio

　21.5 Phases with variable order

　21.6 Ionic solid soluti***

22 Physical solution models

　22.1 Concept of nearest-neiour bond energies

　22.2 Random ming model for a substitutional solutio

　22.3 Deviation from random distributio

　22.4 Short-range order

　22.5 Long-range order

　22.6 Long- and short-range order

　22.7 The compound energy formalism with short-range order

　22.8 Interstitial ordering

　22.9 Composition dependence of physical effects

References

Index

(瑞典)希勒特（M. Hillert），瑞典皇家工学院教授。

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